Generation of pyrrolo[2,3-d]pyrimidines. Unexpected products in the multicomponent reaction of 6-aminopyrimidines, dimedone, and arylglyoxal.

Quiroga, Jairo Y Acosta, Paola A. Y Cruz, Silvia Y Abonía, Rodrigo Y Insuasty, Braulio Y Nogueras, Manuel Y Cobo, Justo (2010) Generation of pyrrolo[2,3-d]pyrimidines. Unexpected products in the multicomponent reaction of 6-aminopyrimidines, dimedone, and arylglyoxal. Tetrahedron Letters (51). pp. 5443-5447. ISSN 0040-4039

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Resumen

A series of 6-aryl-5-(1-cyclohexen-1-yl)pyrrolo[2,3-d]pyrimidines 9a–q were obtained by the three-component reaction between 6-aminopyrimidines 6, 7, 8, dimedone 2, and arylglyoxal 5a,b. The unexpected cyclization process was established by NMR and X-ray diffraction measurements.

Tipo de Elemento: Artículo
Palabras Clave: Pyrrolopyrimidines Multicomponent reaction, Aminopyrimidines, Arylglyoxal Dimedone
Asunto: Q Ciencias > QD Chemistry
Division: Facultad de Ciencias Exactas y Naturales > Programa de Química > Productividad
Depósito de Usuario: Ph D Silvia del Transito Cruz Sánchez
Fecha Deposito: 30 Jan 2017 22:07
Ultima Modificación: 30 Jan 2017 22:07
URI: http://sired.udenar.edu.co/id/eprint/3590

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